Synthesis and crystal structure of a new pyridinium bromide salt: 4-methyl-1-(3-phenoxypropyl)pyridinium bromide

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Synthesis and crystal structure of a new pyridinium bromide salt: 4-methyl-1-(3-phen­oxy­prop­yl)pyridinium bromide

In the cation of the title mol-ecular salt, C15H18NO+·Br-, the pyridinium and phenyl rings are inclined to one another by 11.80 (8)°. In the crystal, the Br- anion is linked to the cation by a C-H⋯Br hydrogen bond. The cations stack along the b-axis direction and are linked by further C-H⋯Br inter-actions, and offset π-π inter-actions [inter-centroid distances = 3.5733 (19) and 3.8457 (19) Å], ...

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Crystal structure of 4-amino-1-(4-methyl­benz­yl)pyridinium bromide

The title mol-ecular salt, C13H15N2 (+)·Br(-), crystallized with two independent ion pairs (A and B) in the asymmetric unit. In the cations, the planes of the pyridine and benzene rings are inclined to one another by 79.32 (8) and 82.30 (10)° in ion pairs A and B, respectively. In the crystal, the anions and cations are connected by N-H⋯Br hydrogen bonds, forming a centrosymmetric tetra-mer-lik...

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4-(4-Nitro­benzene­sulfonamido)pyridinium bromide

In the title compound, C(11)H(10)N(3)O(4)S(+)·Br(-), the benzene ring makes an angle of 88.4 (2)° with the pyridinium ring. The dihedral angle between the nitro group and the benzene ring is 16.5 (2)°. The ions in the crystal structure are linked by a combination of inter-molecular N-H⋯Br and non-conventional C-H⋯Br and C-H⋯O hydrogen bonds, forming a three-dimensional network.

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5-Carbamoyl-2-methyl-1-(2-methyl­benz­yl)pyridinium bromide

In the title mol-ecular salt, C(15)H(17)N(2)O(+)·Br(-), the benzene and pyridinium rings form a dihedral angle of 83.0 (1)°. In the crystal, N-H⋯Br and N-H⋯O hydrogen bonds link the components into chains along [010]. These chains are linked by weak C-H⋯O and C-H⋯Br hydrogen bonds, forming a three-dimensional network.

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Crystal structure of 3-amino-1-propyl­pyridinium bromide

The title mol-ecular salt, C8H13N2 (+)·Br(-), crystallizes with two independent 3-amino-pyridinium cations and two bromide anions in the asymmetric unit (Z' = 2). In the pyridine ring, the N atom is alkyl-ated by a propyl group. The dihedral angle between the mean planes of the pyridinium ring and the propyl group is 84.84 (2)° in cation A, whereas the corresponding angle is 89.23 (2)° in catio...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Crystallographic Communications

سال: 2017

ISSN: 2056-9890

DOI: 10.1107/s2056989017015481